Heat Transfer
Heat transfer occurs by natural convection because change in temperature causes difference in

Density
Thermal conductivity
Heat capacity
Viscosity

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Heat Transfer
In sub-cooled boiling,

Temperature of the heating surface is more than the boiling point of the liquid
Very large vapour space is necessary
Temperature of the heating surface is less than the boiling point of the liquid
Bubbles from heating surface are absorbed by the mass of the liquid

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