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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
Generation of heat by friction is an example of a/an __________ change.

Isothermal
Irreversible
Reversible
Adiabatic

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Chemical Engineering Thermodynamics
For the reversible exothermic reaction, N₂ + 3H₂ ⇋ 2NH₃, increase of pressure would

Both B and C
Give higher yield of NH₃
Shift the equilibrium towards right
Neither A nor B

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Chemical Engineering Thermodynamics
The expression for entropy change, ΔS = n Cp . ln (T₂/T₁), is valid for the __________ of a substance.

Cooling
Heating
Both B and C
Simultaneous pressure & temperature change

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Chemical Engineering Thermodynamics
The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x₁. x₂, where A is a constant. The corresponding equation for ln y₁, where y₁ is the activity co-efficient of component 1, is

A . x₂²
Ax₂
Ax₁²
Ax₁

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Chemical Engineering Thermodynamics
Sublimation temperature of dry ice (solid CO₂) is __________ °C.

0
-273
-78
5

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Chemical Engineering Thermodynamics
For water at 300°C, it has a vapour pressure 8592.7 kPa and fugacity 6738.9 kPa Under these conditions, one mole of water in liquid phase has a volume of 25.28 cm³ and that in vapour phase in 391.1 cm³.Fugacity of water (in kPa) at 9000 kPa will be

6753.5
7058.3
6738.9
9000

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