Chemical Process
Function of sodium thiosulphate (hypo) in development of photographic film/plate is to

Convert silver chloride to silver
Remove metallic silver
Brighten the faint images
Remove unexposed silver halide

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Chemical Process
Liquefaction of gases can not be done by

Adiabatic expansion against a piston or in a turbine
Adiabatic expansion through a throttle valve (Joule-Thomson expansion)
Exchange of heat with colder stream
Merely compressing it beyond critical pressure

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