Chemical Engineering Thermodynamics
The second law of thermodynamics states that

The total energy of system and surrounding remains the same
The energy change of a system undergoing any reversible process is zero
It is not possible to transfer heat from a lower temperature to a higher temperature
None of these

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Chemical Engineering Thermodynamics
Free energy

Decreases in all spontaneous (or irreversible) processes
Remains unchanged in reversible processes carried at constant temperature and pressure
Change during a spontaneous process has a negative value
All of these

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