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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
For an ideal gas, the chemical potential is given by

R dlnP
None of these
R dlnf
RT dlnP

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Chemical Engineering Thermodynamics
The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is

(∂T/∂V)S = -(∂P/∂S)V
(∂S/∂P)T = -(∂V/∂T)P
(∂S/∂V)T = (∂P/∂T)V
(∂V/∂S)P = (∂T/∂P)S

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Chemical Engineering Thermodynamics
In a P-V diagram (for an ideal gas), an isothermal curve will coincide withan adiabatic curve (through a point), when

Cp ≥ Cv
Cp = Cv
Cp > Cv
Cp < Cv

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Chemical Engineering Thermodynamics
Normal temperature and pressure (N.T.P.) corresponds to

20°C and 760 mm Hg
0°C and 760 mm Hg
15°C and 760 mm Hg
0°C and 1 kgf/cm²

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Chemical Engineering Thermodynamics
Gibbs free energy of a pure fluid approaches __________ as the pressure tends to zero at constant temperature.

Zero
Minus infinity
None of these
Infinity

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Chemical Engineering Thermodynamics
When a gas is expanded from high pressure region to low pressure region ; temper -ature change occurs. This phenomenon is related to the

Gibbs-Duhem equation
Gibbs-Helmholtz equation
Third law of thermodynamics
Joule-Thomson effect

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