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Stoichiometry

Stoichiometry
For a reacation, X → Y, if the concentration of 'X' is tripled; the rate becomes nine times. The order of reaction is

3
2
1

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Stoichiometry
The value of Trouton's ratio (λb/Tb) for a number of substances is 21 (where, λb = molal that of vaporisation of a substance at its normal boiling point, KCal/kg. mole and Tb = normal boiling point, °K). The Kis-tyakowsky equation is used for calculation of Trouton's ratio of __________ liquids.

Polar
Neither A nor B
Non-polar
Both A & B

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Stoichiometry
With rise in temperature, the heat capacity of a substance

Increases
Remains unchanged
Decreases
Either A or B; depends on the substance

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Stoichiometry
Claussius Clapeyron equation applies to the __________ process.

Vaporisation
Melting
Sublimation
All of these

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Stoichiometry
A very dilute solution is prepared by dissolving 'x1' mole of solute in 'x2' mole of a solvent. The mole fraction of solute is approximately equal to

X2/x1
1/x2
1 - (x1/x2)
X1/x2

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Stoichiometry
The vapor pressure of a substance, at its melting point, is __________ in the solid state as compared to that in the liquid state.

Less
Either A or B; depends on the nature of the substance
Same
More

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