Chemical Reaction Engineering
For a first order isothermal chemical reaction in a porous catalyst, the effectiveness factor is 0.3. The effectiveness factor will increase if the

Catalyst size is reduced or the catalyst diffusivity is reduced
Catalyst size is increased or the catalyst diffusivity is increased
Catalyst size is increased or the catalyst diffusivity is reduced
Catalyst size is reduced or the catalyst diffusivity is increased

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Chemical Reaction Engineering
Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants ; but it is a function of reaction temperature. In a chemical reaction, the time required to reduce the concentration of reactant from 100 gm moles/litre to 50 gm moles/litre is same as that required to reduce it from 2 gm moles/litre to 1 gm mole/litre in the same volume. Then the order of this reaction is