Chemical Engineering Thermodynamics
Pick out the wrong statement pertaining to the decomposition of PCl5 represented by, PCl5 ⇋ PCl3 + Cl₂.Degree of dissociation of PCl5 will

None of these
Increase on addition of an inert gas at constant pressure
Decrease on addition of Cl₂
Decrease on increasing the pressure of the system

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Chemical Engineering Thermodynamics
It is desired to bring about a certain change in the state of a system by performing work on the system under adiabatic conditions.

The amount of work needed is independent of path
Work alone can not bring out such a change of state
The amount of work needed is path dependent
More information is needed to conclude anything about the path dependence or otherwise of the work needed

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