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ELECTROLYSIS AND STORAGE BATTERIES

Electrolysis and Storage Batteries
During the charging and discharging of a nickel-iron cell

corrosive fumes are produced
its e.m.f. remains constant
nickel hydroxide remains unsplit
water is neither formed nor absorbed

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Electrolysis and Storage Batteries
Excessive charging a battery tends to

increase the internal resistance of the battery
produce gassing
bring about all above changes
to corrode the positive plates into lead peroxide thereby weakening them physically

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Electrolysis and Storage Batteries
As compared to constant-current system, the constant-voltage system of charging a lead acid cell has the advantage of

increasing cell capacity
reducing time of charging
Both of the listed here
avoiding excessive gassing

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Electrolysis and Storage Batteries
Charging a sulphated battery at high rate results in

warping of plates
All of the listed here
damage to separators, cell caps covers and battery case due to excessive temperature
boiling of electrolyte due to gassing

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Electrolysis and Storage Batteries
During the idle period of the battery, strong electrolyte tends to change the active material of the cell into

PbSC-4
Pb
PbO
Pb02

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