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ELECTROLYSIS AND STORAGE BATTERIES

Electrolysis and Storage Batteries
During the charging and discharging of a nickel-iron cell

nickel hydroxide remains unsplit
water is neither formed nor absorbed
its e.m.f. remains constant
corrosive fumes are produced

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Electrolysis and Storage Batteries
Excessive charging a battery tends to

increase the internal resistance of the battery
bring about all above changes
produce gassing
to corrode the positive plates into lead peroxide thereby weakening them physically

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Electrolysis and Storage Batteries
As compared to constant-current system, the constant-voltage system of charging a lead acid cell has the advantage of

increasing cell capacity
reducing time of charging
avoiding excessive gassing
Both of the listed here

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Electrolysis and Storage Batteries
Charging a sulphated battery at high rate results in

boiling of electrolyte due to gassing
All of the listed here
warping of plates
damage to separators, cell caps covers and battery case due to excessive temperature

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Electrolysis and Storage Batteries
During the idle period of the battery, strong electrolyte tends to change the active material of the cell into

Pb02
Pb
PbSC-4
PbO

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