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ELECTROLYSIS AND STORAGE BATTERIES

Electrolysis and Storage Batteries
During the charging and discharging of a nickel-iron cell

water is neither formed nor absorbed
corrosive fumes are produced
its e.m.f. remains constant
nickel hydroxide remains unsplit

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Electrolysis and Storage Batteries
Excessive charging a battery tends to

produce gassing
bring about all above changes
increase the internal resistance of the battery
to corrode the positive plates into lead peroxide thereby weakening them physically

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Electrolysis and Storage Batteries
As compared to constant-current system, the constant-voltage system of charging a lead acid cell has the advantage of

Both of the listed here
reducing time of charging
increasing cell capacity
avoiding excessive gassing

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Electrolysis and Storage Batteries
Charging a sulphated battery at high rate results in

damage to separators, cell caps covers and battery case due to excessive temperature
All of the listed here
warping of plates
boiling of electrolyte due to gassing

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Electrolysis and Storage Batteries
During the idle period of the battery, strong electrolyte tends to change the active material of the cell into

Pb
PbSC-4
Pb02
PbO

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