Chemical Engineering Thermodynamics
Compressibility factor-reduced pressure plot on reduced co-ordinates facilitates

More accurate plotting
Use of only one graph for all gases
Easier plotting
Covering of wide range

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Chemical Engineering Thermodynamics
Free energy

Remains unchanged in reversible processes carried at constant temperature and pressure
Change during a spontaneous process has a negative value
Decreases in all spontaneous (or irreversible) processes
All of these

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Chemical Engineering Thermodynamics
If the heat of solution of an ideal gas in a liquid is negative, then its solubility at a given partial pressure varies with the temperature as

Solubility is independent of temperature
Solubility increases as temperature decreases
Solubility increases or decreases with temperature depending on the Gibbs free energy change of solution
Solubility increases as temperature increases

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