MS Excel
You can set Page Border in Excel from

From Border tool in Formatting toolbar
You can not set Page Border in Excel
From Border tab in Farmat cells dialog box
From Line style tool in Drawing toolbar

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MS Excel
How do you select an entire column?

Select Edit > Select > Column from the menu
Click the column heading letter
Hold down the Ctrl key as you click anywhere in the column
Hold down the shift key as you click anywhere in the column

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