Chemical Engineering Thermodynamics
Clayperon equation deals with the

Temperature dependence of heat of phase transition
Calculation of ΔF for spontaneous phase change
Rate of change of vapour pressure with temperature
Effect of an inert gas on vapour pressure

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Chemical Engineering Thermodynamics
Gibbs-Duhem equation

Applies only to binary systems
States that n₁dμ₁ + n₂dμ₂ + ....njdμj = 0, for a system of definite composition at constant temperature and pressure
None of these
Finds no application in gas-liquid equilibria involved in distillation

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