Chemistry
Chile saltpeter is the common name of:

Sodium nitrite
Potassium nitrate
Sodium nitrate
Potassium nitrite

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Chemistry
Water is not effective in extinguishing a fire caused by petrol because

The flame is too hot for water to cool it down
Water and petrol are immiscible with each other and petrol which forms the upper layer continues to burn
Water and petrol react chemically
Water and petrol are miscible with each other

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