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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
At triple point (for one component system), vapour pressure of solid as compared to that of liquid will be

Less
More or less ; depending on the system
More
Same

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Chemical Engineering Thermodynamics
In any spontaneous process,

Only F decreases
Both F and A increase
Both F and A decreases
Only A decreases

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Chemical Engineering Thermodynamics
The reaction A (l) R(g) is allowed to reach equilibrium conditions in an autoclave. At equilibrium, there are two phases, one a pure liquid phase of A and the other a vapor phase of A, R and S. Initially A alone is present. The number of degrees of freedom are

2
3
1

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Chemical Engineering Thermodynamics
In case of a close thermodynamic system, there is __________ across the boundaries.

Mass and energy transfer
No mass transfer but heat transfer
No heat and mass transfer
None of these

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Chemical Engineering Thermodynamics
Fugacity is most helpful in

The study of chemical equilibria involving gases at atmospheric pressure
Representing actual behaviour of real gases
Representing actual behaviour of ideal gases
None of these

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Chemical Engineering Thermodynamics
__________ explains the equilibrium constant for any chemical reaction.

Henry's law
None of these
Hess's law
Law of mass action

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