Chemical Reaction Engineering
At a given temperature, K₁, K₂ and K3 are equilibrium constants for the following reactions 1, 2, 3 respectively. CH₄(g) + H₂O(g) ⇋ CO(g) + 3H₂(g), CO(g) + H₂O(g) ⇋ CO₂(g) + H₂(g) CH₄(g) + 2H₂O(g) ⇋ CO₂(g) + 4H₂(g) Then K₁, K₂ and K3 are related as:

K3(K₁+K₂)/2
K3 = (K₁.K₂)0.5
K3 = K₁.K₂
K3 = (K₁.K₂)2

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Chemical Reaction Engineering
For a tubular reactor with space time 'τ' and residence time 'θ', the following statement holds good.

τ = θ , for an isothermic tubular reactor in which the density of the process fluid is constant
τ = θ , when the fluid density changes in the reactor
τ and θ are always equal
τ = θ , for a non-isothermal reactor

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