Chemical Reaction Engineering
At a given temperature, K₁, K₂ and K3 are equilibrium constants for the following reactions 1, 2, 3 respectively. CH₄(g) + H₂O(g) ⇋ CO(g) + 3H₂(g), CO(g) + H₂O(g) ⇋ CO₂(g) + H₂(g) CH₄(g) + 2H₂O(g) ⇋ CO₂(g) + 4H₂(g) Then K₁, K₂ and K3 are related as:

K3 = K₁.K₂
K3(K₁+K₂)/2
K3 = (K₁.K₂)0.5
K3 = (K₁.K₂)2

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Chemical Reaction Engineering
The reactions of high molecularity are rare, because

Many body collisions are not favoured energetically
Of very large activation energy of many bodies
Of low probability of many body collisions
Of requirement of very large concentration for such reactions

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