Stoichiometry
Assume that benzene is insoluble in water. The normal boiling points of benzene and water are 80.1 and 100°C respectively. At a pressure of 1 atm, the boiling point of a mixture of benzene and water is

100°C
Greater than 80.1°C but less than 100°C
80.1°C
Less than 80.1°C

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Stoichiometry
According to Raoult's law, "The vapor pressure exerted by component in a solution is proportional to the mole fraction of that component." Raoult's law is not applicable under the following assumption/condition.

The component molecules are non polar and are of almost equal size
In the formation of solution, chemical combination/molecular association between unlike molecules takes place
The attractive forces between like and unlike molecules are almost equal
No component is concentrated at the surface of the solution

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