Physics
An oil drop spreads over water because

water has a higher surface tension
Oil is lighter than water
Oil is more viscous
Oil does not mix with water

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Physics
Siphon will fail to work if:

The level of the liquid in the two vessels are at the same height.
The densities of the liquid in the two vessels are equal.
Both its limbs are of unequal length.
The temperature of the liquids in the two vessels are the same.

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