Mass Transfer
Relative volatility varies with the concentration of component for an ideal solution. The relative volatity of a binary mixture may be defined as the ratio of vapor pressure of component 'A' to that of component 'B', when

Only vapor phase follows Raoult's law
Only liquid phase obeys Dalton's law
Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law
Liquid phase obeys Dalton's law and vapor phase obeys Raoult's law

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Mass Transfer
One mole feed of a binary mixture of a given composition is flash vaporised at a fixed P and T. If Raoult's law is obeyed, then changing the feed composition would effect

The product composition as well as the fraction vaporised
Neither the product composition nor the fraction vaporised
The fraction vaporised but not the product composition
The product composition but not the fraction vaporised

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