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Chemical Engineering Thermodynamics

Chemical Engineering Thermodynamics
A cyclic engine exchanges heat with two reservoirs maintained at 100 and 300°C respectively. The maximum work (in J) that can be obtained from 1000 J of heat extracted from the hot reservoir is

349
667
651
1000

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Chemical Engineering Thermodynamics
Free energy changes for two reaction mechanism 'X' and 'Y are respectively - 15 and - 5 units. It implies that X is

Slower than Y
Three times slower than Y
Three times faster than Y
Faster than Y

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Chemical Engineering Thermodynamics
The number of degree of freedom for an azeotropic mixture of ethanol and water in vapour-liquid equilibrium, is

0
1
2
3

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Chemical Engineering Thermodynamics
(∂T/∂P)H is the mathematical expression for

Joule-Thompson co-efficient
None of these
Specific heat at constant pressure (Cp)
Specific heat at constant volume (Cv)

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Chemical Engineering Thermodynamics
At triple point (for one component system), vapour pressure of solid as compared to that of liquid will be

More or less ; depending on the system
Less
Same
More

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Chemical Engineering Thermodynamics
The theoretical minimum work required to separate one mole of a liquid mixture at 1 atm, containing 50 mole % each of n- heptane and n- octane into pure compounds each at 1 atm is

0.5 RT
2 RT
-RT ln 0.5
-2 RT ln 0.5

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