Fuels and Combustion
A coal with high ash content is undesirable, as

The ash in molten condition gets absorbed in the pores of the refractory lining of the furnace and causes its spalling due to different co-efficient of expansion/contraction of the refractory and the
The ash retains the sulphur & phosphorus and thus affects the quality of products in metallurgical furnace apart from increasing the slag volume. Besides, it may fuse and stick to the boiler tubes
It is abrasive to the coal pulveriser (ie.g. ball mill) and the combustion chamber
All of these

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Fuels and Combustion
Rate of low temperature oxidation of coal due to bad storage conditions

Is more for low volatile coal compared to high volatile coal
Does not vary with increase in surface area
Is accelerated by storage in large heaps with small surface to volume ratio
Decreases with increase in surface area

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