Stoichiometry
A car tyre of volume 0.057 m³ is inflated to 300 kPa at 300 K. After the car is driven for 10 hours, the pressure in the tyre increases to 330 kPa. Assume air is an ideal gas and Cv for air is 21 J/mole.K. The change in the internal energy of air in the tyre in J/mole is

760
630
880
380

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Stoichiometry
According to Raoult's law, "The vapor pressure exerted by component in a solution is proportional to the mole fraction of that component." Raoult's law is not applicable under the following assumption/condition.

No component is concentrated at the surface of the solution
The component molecules are non polar and are of almost equal size
The attractive forces between like and unlike molecules are almost equal
In the formation of solution, chemical combination/molecular association between unlike molecules takes place

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